|
Atomistry » Zinc » Chemical Properties » Zinc Selenide | ||
Atomistry » Zinc » Chemical Properties » Zinc Selenide » |
Zinc Selenide, ZnSe
Zinc Selenide, ZnSe, is produced by heating zinc and selenium together at a high temperature. The amorphous substance thus produced has a brilliant yellow colour, is infusible up to 1100° C., and has a density of 5.29 at 21° C. It is more easily obtained by heating zinc in a current of hydrogen selenide.
Reddish-yellow crystals, of density 5.40 and belonging to the regular system, were obtained by subliming the amorphous form in a current of hydrogen. Yellow crystals of density 5.42 at 15° C. were obtained by heating precipitated zinc selenide, dried in a current of hydrogen, in the electric furnace, and a partially crystalline ZnSe was prepared by similarly heating a mixture of zinc selenate and carbon. Crystals belonging to the hexagonal system were obtained by heating zinc chloride vapour with a mixture of nitrogen and hydrogen selenide. Zinc selenide is thus dimorphous analogously to zinc sulphide. Needle-shaped crystals were also obtained by reducing highly heated zinc selenate with hydrogen. Crystalline zinc selenide dissolves (evolving hydrogen selenide) in aqueous hydrochloric acid, though gaseous hydrogen chloride, even at a high temperature, has no action on it. It burns in oxygen, forming a basic selenite and selenium dioxide. Chlorine displaces selenium from it. [Zn] + [Se] = [ZnSe] (cryst.)+40.4 Cal. The corresponding figures for precipitated ZnSe are 34.0 (crystalline) and 33.60 (amorphous). |
Last articlesZn in 9JYWZn in 9IR4 Zn in 9IR3 Zn in 9GMX Zn in 9GMW Zn in 9JEJ Zn in 9ERF Zn in 9ERE Zn in 9EGV Zn in 9EGW |
© Copyright 2008-2020 by atomistry.com | ||
Home | Site Map | Copyright | Contact us | Privacy |